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Studies on polyhaloalkanes. II. A facile method for mono‐fluorination of α, ω‐dihaloperfluoroalkanes
Author(s) -
Huang BingNan,
Prescher Dietrich
Publication year - 1993
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19930110212
Subject(s) - chemistry , anhydrous , antimony , chlorine , organic chemistry , reaction conditions , trifluoride , fractionation , catalysis
A facile monofluorination of α, ω‐dihaloperfluoroalkanes was achieved by the reaction of them with antimony trifluoride and chlorine in anhydrous antimony pentachloride when monofluorinated products were removed immediately after their formation from the reaction mixture by fractionation. The reaction conditions were also investigated.