Premium
Studies on sulfinatodehalogenation XXIV. Further study on sodium dithionite‐initiated perfluoroalkylation of electron‐rich aromatics
Author(s) -
Huang WeiYuan,
Ma WuPing
Publication year - 1992
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19920100213
Subject(s) - chemistry , sodium dithionite , phenols , medicinal chemistry , organic chemistry
The application of the sulfinatodehalogenation reaction system for the perfluoroalkylation of electron‐rich aromatics is further studied. It was shown that perfluoroalkyl iodides reacted with polyhydric phenols, N,N −dialkylanilines, 2,5‐dimethylpyrrole, N −methylpyrrole initiated by Na 2 S 2 O 4 −NaHCO 3 gave the corresponding perfluoroalkylated products in moderate to good yields.