Photoaddition of chloroform to ketones via a singlet exciplex: A photo‐CIDNP study | Zendy

Zhang MaoXi | Zendy; Yang Li | Zendy; Liu ZhongLi | Zendy; Liu YouCheng | Zendy

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Photoaddition of chloroform to ketones via a singlet exciplex: A photo‐CIDNP study

Author(s) -

Zhang MaoXi,

Yang Li,

Liu ZhongLi,

Liu YouCheng

Publication year - 1991

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19910090108

Subject(s) - chemistry , cidnp , excimer , photochemistry , ketone , singlet state , photodissociation , chloroform , singlet oxygen , fluorescence , organic chemistry , polarization (electrochemistry) , excited state , optics , physics , oxygen , nuclear physics

Photolysis of 4‐acetyl‐4‐ethoxyformylcyclohexanone, 4‐acetyl‐4‐phenylcyclohexanone and 1‐acetyl‐1‐phenylcyclohexane in deuteriochloroform using a high pressure Hg—Xe lamp showed unusual polarizations. The results are explained by the formation of a singlet exciplex of the ketone with deuteriochloroform and the photoaddition of deuteriochloroform to the ketone.

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