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Asymmetric carbonyl addition with the homochiral ketimine derived from (+) or (−)‐pinanone and benzylamine
Author(s) -
Mi AiQiao,
Chen YuanWei,
Wang Jing,
Yang GuiShu,
Jiang YaoZhong
Publication year - 1990
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19900080612
Subject(s) - benzylamine , chemistry , optically active , organic chemistry
The carbonyl addition of the pinanone ketimine derived from (+) or (−)‐2‐hydroxy‐pinan‐3‐one and benzylamine has been studied and the optically active α,β‐substituted‐β‐aminoethanol derivatives were obtained in good chemical yields (36.5‐69.5%) with optical purity ranging from 1.4% to 99.9%.
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