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Studies on the alcohol exchange reactions of methoxide ditungsten [W(IV)] compound W 2 Cl 4 (OCH 3 ) 4 (CH 3 OH) 2 , prepared from ( n ‐Bu 4 N) 3 W 2 Cl 9
Author(s) -
Hong Bo,
Jin SongLin,
YihTong Gu, YiDong Ku,
Chen MingQin
Publication year - 1990
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19900080606
Subject(s) - chemistry , methoxide , alcohol , medicinal chemistry , cluster (spacecraft) , stereochemistry , methanol , crystallography , organic chemistry , computer science , programming language
( n ‐Bu 4 N) 3 W 2 Cl 9 , prepared from K 3 W 2 Cl 9 , can be readily converted to a series of [W(IV)] cluster compounds, W 2 Cl 4 (μ‐OR) 2 (OR') 2 (R'OH) 2 , including seven known compounds and two new compounds with R=Me, R'= i ‐Pr and sec ‐Bu. The crystallographic data of 7 and 8 are hereby presented.