Studies on the alcohol exchange reactions of methoxide ditungsten [W(IV)] compound W 2 Cl 4 (OCH 3 ) 4  (CH 3 OH) 2 , prepared from ( n ‐Bu 4 N) 3 W 2 Cl 9 | Zendy

Hong Bo | Zendy; Jin SongLin | Zendy; YihTong Gu, YiDong Ku | Zendy; Chen MingQin | Zendy

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Studies on the alcohol exchange reactions of methoxide ditungsten [W(IV)] compound W 2 Cl 4 (OCH 3 ) 4 (CH 3 OH) 2 , prepared from ( n ‐Bu 4 N) 3 W 2 Cl 9

Author(s) -

Hong Bo,

Jin SongLin,

YihTong Gu, YiDong Ku,

Chen MingQin

Publication year - 1990

Publication title -

chinese journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 1001-604X

DOI - 10.1002/cjoc.19900080606

Subject(s) - chemistry , methoxide , alcohol , medicinal chemistry , cluster (spacecraft) , stereochemistry , methanol , crystallography , organic chemistry , computer science , programming language

( n ‐Bu 4 N) 3 W 2 Cl 9 , prepared from K 3 W 2 Cl 9 , can be readily converted to a series of [W(IV)] cluster compounds, W 2 Cl 4 (μ‐OR) 2 (OR') 2 (R'OH) 2 , including seven known compounds and two new compounds with R=Me, R'= i ‐Pr and sec ‐Bu. The crystallographic data of 7 and 8 are hereby presented.

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