Premium
A study on the sulfenylchlorination of cembrene and the related cembranoids
Author(s) -
ZhuJin Liu,
YunLong Li,
QingZhi Chen,
WeiQi Wang
Publication year - 1990
Publication title -
chinese journal of chemistry
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19900080415
Subject(s) - chemistry , stereochemistry
p ‐Tolylsulfenyl chloride adds regioselectively at the C(11) C(12) bond of cembrene 1 to give 11‐( R )‐ p ‐tolylthio‐1‐( S )‐cembra‐2 E , 4 Z , 7 E , 12(20)‐tetraene 2 following a rapid HCl elimination. Two new cembranoids, 1‐( S )‐cembra‐2 E , 4 Z , 7 E , 12(20)‐tetraene 3 and 1‐( S )‐cembra‐2 E , 4 Z , 7 E , 11 Z ‐tetraen‐20‐ol 4 are prepared from 2.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom