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A study on the sulfenylchlorination of cembrene and the related cembranoids
Author(s) -
ZhuJin Liu,
YunLong Li,
QingZhi Chen,
WeiQi Wang
Publication year - 1990
Publication title -
chinese journal of chemistry
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19900080415
Subject(s) - chemistry , stereochemistry
p ‐Tolylsulfenyl chloride adds regioselectively at the C(11) C(12) bond of cembrene 1 to give 11‐( R )‐ p ‐tolylthio‐1‐( S )‐cembra‐2 E , 4 Z , 7 E , 12(20)‐tetraene 2 following a rapid HCl elimination. Two new cembranoids, 1‐( S )‐cembra‐2 E , 4 Z , 7 E , 12(20)‐tetraene 3 and 1‐( S )‐cembra‐2 E , 4 Z , 7 E , 11 Z ‐tetraen‐20‐ol 4 are prepared from 2.