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Rongalite‐initiated addition of perfluoroalkyl iodides to olefins
Author(s) -
BingNan Huang,
JinTao Liu
Publication year - 1990
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19900080413
Subject(s) - chemistry , acetonitrile , adduct , sodium bicarbonate , aqueous solution , radical , organic chemistry , bicarbonate , medicinal chemistry
Abstract Perfluoroalkyl iodides reacted with olefins in aqueous acetonitrile in the presence of Rongalite‐sodium bicarbonate under mild conditions to give the corresponding 1:1 adducts in moderate to high yields. The formation of these products and the orientation of the addition seemed to show that radicals took part in the reaction. This provides a convenient method for perfluoroalkylation.