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Studies on organo‐phosphorus, ‐arsonic, and ‐antimony polytungstates and polymolybdates: VI. A new guanidinium hexamolybdobisphenylarsonate monohydrate (CN 3 H 6 ) 5 [(C 6 H 5 As) 2 Mo 6 O 25 H]·H 2 O
Author(s) -
BenYao Liu,
YihTong Gu, YiDong Ku,
Ming Wang,
PeiJu Zheng
Publication year - 1990
Publication title -
chinese journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 1001-604X
DOI - 10.1002/cjoc.19900080206
Subject(s) - chemistry , monoclinic crystal system , isostructural , antimony , salt (chemistry) , tungsten , molybdenum , crystallography , electrochemistry , crystal structure , inorganic chemistry , infrared spectroscopy , phosphorus , organic chemistry , electrode
A new guanidinium hexamolybdobisphenylarsonate which is quite different from that reported in literature has been synthesized and characterized. This new salt which is isostructural with its tungsten congener crystallized as monoclinic, space group P 2 1 / a with cell dimensions of a =15.005 (1), b = 17.559(1), c = 18.008(2) Å, β = 97.24(1)°. Its elemental analyses, IR and UV spectra have been reported and discussed. Its thermal properties and electrochemical behavior have also been reported.