The enantioselective synthesis of (4 S ,5 S )‐ and (4 S ,5 R )‐5‐hydroxy‐4‐decanolide, the autoregulators from  Strepotomyces griseus | Zendy

Jiang YanYing | Zendy; Fong WeiLin | Zendy; Ding WeiJue | Zendy; Lin GuoQiang | Zendy

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The enantioselective synthesis of (4 S ,5 S )‐ and (4 S ,5 R )‐5‐hydroxy‐4‐decanolide, the autoregulators from Strepotomyces griseus

Author(s) -

Jiang YanYing,

Fong WeiLin,

Ding WeiJue,

Lin GuoQiang

Publication year - 1989

Publication title -

acta chimica sinica english edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.28

H-Index - 41

eISSN - 1614-7065

pISSN - 0256-7660

DOI - 10.1002/cjoc.19890070512

Subject(s) - chemistry , enantioselective synthesis , propargyl alcohol , streptomyces griseus , yield (engineering) , propargyl , stereochemistry , alcohol , organic chemistry , catalysis , streptomyces , materials science , biology , bacteria , metallurgy , genetics

(4 S , 5 S )‐ and (4 S , 5 R )‐5‐Hydroxy‐4‐decanolide ( 1a and 1b ), the proposed autoregulators from Strepotomyces Griseus were synthesized from a propargyl alcohol 2 in an overall yield of 30%, employing the Sharpless asymmetric epoxidation as the key step.

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