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Study on the mechanism of Schiemann reaction by mass spectrometry
Author(s) -
Deng Yan
Publication year - 1989
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19890070507
Subject(s) - chemistry , mass spectrometry , mechanism (biology) , reaction mechanism , combinatorial chemistry , organic chemistry , chromatography , catalysis , philosophy , epistemology
Schiemann reaction of 12 aryl diazonium fluoborates was studied by mass spectrometry. The products and by‐products of the reactions were identified and the possible pathways were explored. It is shown that Schiemann reaction proceeds by free‐radical mechanism.