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The reactions of perfluoroalkanesulfinates: II. A new method for the synthesis of N, N ‐bisperfluoroalkylhydroxylamine 1
Author(s) -
WeiYuan Huang,
LiQing Hu,
WenZheng Ge
Publication year - 1988
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19880060213
Subject(s) - chemistry , nitric acid , nitrous acid , yield (engineering) , amide , nitrogen , nitrogen dioxide , sodium , nuclear chemistry , inorganic chemistry , organic chemistry , medicinal chemistry , materials science , metallurgy
The reaction of sodium or silver perfluoroalkanesulfinate with nitric acid, nitrous acid or nitrogen dioxide in aqueuos solution gave a moderate yield of N, N ‐bisperfluoroalkylhydroxylamine accompanied by perfluorocarboxylic acid, amide and nitrosoperfluoroalkane.
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