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Study on the kinetics of isomerization of some unsymmetrical bis(μ‐alkylthio) hexacarbonyldiiron by NMR method
Author(s) -
Zhang QiYan,
Zhu ChengYue,
Song LiCheng,
Chen RongTi,
Chen Y. T.,
Lu XiuQing,
Li GuoWei
Publication year - 1988
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19880060105
Subject(s) - chemistry , isomerization , kinetics , proton nmr , carbon 13 nmr , computational chemistry , photochemistry , medicinal chemistry , organic chemistry , catalysis , physics , quantum mechanics
The kinetics of the isomerization of (μ‐PhCH 2 S) (μ‐RS)Fe 2 (CO) 6 (RMe, Et) and (μ‐PhCH 2 S) (μ‐ t ‐BuS)Fe 2 (CO) 6 has been studied by conventional and dynamic NMR methods respectively. A possible mechanism for the reaction has been proposed and the factors which influence the reaction rate have been discussed.