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Studies on organosilicon reactive intermediates: I. Photochemical generation of furylsilylene
Author(s) -
ShiHui Wu,
Ge Wu,
FengGang Tao,
ZiSen Lin
Publication year - 1987
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19870050406
Subject(s) - organosilicon , chemistry , cyclohexene , reactive intermediate , methanol , derivative (finance) , photochemistry , ring (chemistry) , organic chemistry , catalysis , financial economics , economics
A new type of organosilicon reactive intermediate, α‐furylphenylsilylene was generated from 2‐(α‐furyl)‐2‐phenylhexamethyltrisilane. When α‐furylphenylsilylene reacted with 2,3‐dimethyl‐1,3‐butadiene, the corresponding addition and insertion products were obtained. The intermediate silirane derivative from the reaction of α‐furylphenylsilylene with cyclohexene was ring‐opened by methanol to give α‐furylphenyl cyclohexylmethoxylsilane.