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Studies on sulfinatodehalogenation: IX. Synthesis and reaction of secondary perfluoroalkyl iodides
Author(s) -
WeiYuan Huang,
Wei Wang
Publication year - 1986
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19860040313
Subject(s) - chemistry , sodium dithionite , yield (engineering) , adduct , medicinal chemistry , organic chemistry , metallurgy , materials science
Several derivatives of secondary perfluoroalkyl iodides such as CF 3 CFI(CF 2 ) 2 O(CF 2 ) 3 SO 2 F (3), CF 3 CFI(CF 2 ),O(CF 2 ) 2 SO 3 Na (4), CF 3 CFI(CF 3 ) n Cl ( n =2, 7a; n =4, 7b) and CF 3 (CF2) 2 ‐OCFICF 3 (8) were synthesized using known methods, their reaction with sodium dithionite was studied and various olefins were added into the reaction system as radical traps to yield the 1:1 radical adducts.