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Studies on the optical analogues of zoapatanol: Synthesis of key intermediate (2 S ,3 R )‐2‐citronellyl‐6‐methylene‐heptan‐2,3,7‐triol
Author(s) -
YuQun Chen,
LiXian Gan,
YeChun Wen,
YunWen Wang,
XiMing Zhang,
GuoQing Mao
Publication year - 1986
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19860040311
Subject(s) - synthon , chemistry , methylene , triol , stereochemistry , organic chemistry , diol
The key intermediate (2 S , 3 R )‐2‐citronellyl‐6‐methylene‐heptan‐2,3,7‐triol (8) of analogues of zoapatanol was synthesized in seven steps from the chiral synthon 2. The absolute configuration of the new chiral centre in compounds 5a‐8 was identified as S by Mukaiyama's method.
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