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On the studies of the vibrational spectra of cluster [Mo 2 O 2 S 2 (S 2 ) 2 ] 2‐
Author(s) -
YingQiu Liang,
WenYun Zhao,
WeiQing Xu,
ZhiGui Zhang
Publication year - 1986
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19860040107
Subject(s) - chemistry , raman spectroscopy , spectral line , ion , cluster (spacecraft) , crystal (programming language) , infrared spectroscopy , infrared , resonance (particle physics) , molecular physics , analytical chemistry (journal) , crystallography , nuclear magnetic resonance , atomic physics , optics , organic chemistry , physics , astronomy , computer science , programming language
IR and Raman spectra of [Mo 2 O 2 S 2 (S 2 ) 2 ] 2‐ were reported. The resonance Raman spectra and the depolarization ratios in CH 3 CN solution were measured. By using the data of crystal structure, the simplified normal coordinate calculation of the stretching vibrations for anion [Mo 2 O 2 S 2 (S 2 ) 2 ] 2‐ was performed. The results obtained are useful to assign the vibrational bands of some Mo‐Fe‐S clusters.