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Energy transfer of n ‐hexane‐tributyl phosphate (TBP) binary system: Using TBP as a probe for the detection of excited states of n ‐hexane
Author(s) -
RongYao Yuan,
XianMing Pan,
JiLan Wu
Publication year - 1985
Publication title -
acta chimica sinica english edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.28
H-Index - 41
eISSN - 1614-7065
pISSN - 0256-7660
DOI - 10.1002/cjoc.19850030104
Subject(s) - hexane , chemistry , excited state , tributyl phosphate , tri n butyl phosphate , energy transfer , analytical chemistry (journal) , molecule , photochemistry , chromatography , atomic physics , extraction (chemistry) , organic chemistry , molecular physics , solvent extraction , physics
Abstract In this paper TBP labeled with 32 P was used as a probe for detecting the excited species of n ‐hexane. Under γ irradiation of n ‐hexane‐TBP binary system, it was found that TBP was sensitized by excited n ‐hexane molecules and a G value of 1.05 was found for the excited state of n ‐hexane. An energy transfer mechanism was proposed and kinetic equation of sensitization was obtained. Theoretical calculation is in agreement with experimental results.