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An approach for the optimization of transient diffusion cell measurements
Author(s) -
Sun Weiruo,
Magalhães Fernão D.,
Costa Carlos A. V.
Publication year - 2001
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450790522
Subject(s) - diffusion , transient (computer programming) , sensitivity (control systems) , parametric statistics , moment (physics) , biological system , computer science , diffusion equation , mathematical optimization , mathematics , electronic engineering , statistics , physics , engineering , thermodynamics , operating system , metric (unit) , operations management , classical mechanics , biology
In a diffusion cell experiment, the presence of a film diffusion resistance, in series with intrapellet diffusion, leads to loss of precision in the estimation of intrapellet diffusivities. A general strategy, extendable to other problems, for quantifying a parametric region where film diffusion resistance can be neglected is studied. The results obtained from different criteria, using both moment and time domain analysis, are compared and discussed. The optimization of the experimental system in terms of maximizing the measurement's sensitivity towards the estimated parameter is also addressed, and general considerations for the optimum design of a diffusion cell system are drawn.