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Ion exchange equilibria in binary and ternary systems
Author(s) -
Boyer William D. A.,
Baird Malcolm H. I.,
Nirdosh I.
Publication year - 1999
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450770115
Subject(s) - ternary operation , binary number , ternary numeral system , selectivity , chemistry , thermodynamics , ion exchange , ion , analytical chemistry (journal) , chromatography , mathematics , physics , organic chemistry , computer science , catalysis , arithmetic , programming language
Simple mathematical models for binary and ternary ion exchange equilibria were developed to predict selectivity coefficients and resin capacities from a simple experiment to within acceptable engineering accuracy limits. Batch equilibrium experimental investigations were undertaken to test the models for binary systems (Ni‐Na, Cu‐Na, Zn‐Na, Cd‐Na and Pb‐Na) and ternary systems (Ni‐Cu‐Na, Cd‐Ni‐Na, Cd‐Cu‐Na and Pb‐Cu‐Na) with a commercial DOWEX HCR‐W2 resin. Binary parameters were used to predict ternary equilibria. It was found that good agreement between the predicted and experimental values was obtained when the binary selectivity coefficients of the two competing heavy metal ions in the ternary system were either almost equal or differed by a factor as large as five.