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The catalytic oxidative coupling of methane: II. Axial gas sample probing in a bubbling Fluidised‐Bed reactor and the effect of side reactions
Author(s) -
Do K. T.,
Edwards J. H.,
Tyler R. J.
Publication year - 1997
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450750213
Subject(s) - oxidative coupling of methane , catalysis , methane , hydrocarbon , selectivity , chemistry , coupling (piping) , chemical engineering , materials science , organic chemistry , composite material , engineering
The atmospheric pressure catalytic oxidative coupling of methane was studied in detail by axial gas concentration probing experiments in a 60 mm OD bubbling fluidised‐bed reactor system. Experimental data demonstrated a very fast reaction which occurred within the vicinity of the distributor (normally in the first 5 mm of bed height) under normal reaction conditions of 850°C and 83 vol%/17 vol% CH 4 /O 2 feed. The data also showed that hydrocarbon selectivity was deleteriously affected by side reactions which were also promoted by the catalysts even though they were good catalysts for the oxidative coupling reaction. If this reduction in hydrocarbon selectivity is inevitable then there will be optimum operating conditions for each catalyst in the bubbling fluidised bed reactor.