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Heats of mixing of amine/alkane and amine/alcohol systems at 288.15 and 308.15 K. Correlation and prediction with AGSM and with the quasi‐chemical theory
Author(s) -
Chamblain J. F.,
Vera J. H.
Publication year - 1988
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450660317
Subject(s) - mixing (physics) , alkane , nonane , chemistry , amine gas treating , heptane , thermodynamics , dilution , isothermal process , alcohol , calorimeter (particle physics) , unifac , group contribution method , work (physics) , organic chemistry , activity coefficient , hydrocarbon , physics , phase equilibrium , aqueous solution , quantum mechanics , detector , optics , phase (matter)
Experimental heats of mixing data for n‐amylamine with n‐heptane and n‐nonane and with 1‐hexanol, 1‐octanol and 1‐decanol at 288.15 and 308.15 K are reported. The data were obtained using a semicontinuous isothermal dilution Van Ness type calorimeter. Experimental data from this work along with the data from other sources were used to test the predictive potential of the Analytical Group Solution Model (AGSM) and of the Quasi‐Chemical theory.