Vapor‐liquid equilibrium, excess gibbs energy and excess enthalpy of 1, 3 dioxolane‐methylcyclohexane at  t  = 313.15 k | Zendy

Castellari Carlo | Zendy; Francesconi Romolo | Zendy; Comelli Fabio | Zendy

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Vapor‐liquid equilibrium, excess gibbs energy and excess enthalpy of 1, 3 dioxolane‐methylcyclohexane at t = 313.15 k

Author(s) -

Castellari Carlo,

Francesconi Romolo,

Comelli Fabio

Publication year - 1988

Publication title -

the canadian journal of chemical engineering

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.404

H-Index - 67

eISSN - 1939-019X

pISSN - 0008-4034

DOI - 10.1002/cjce.5450660119

Subject(s) - methylcyclohexane , enthalpy , dioxolane , gibbs free energy , cyclohexanone , cyclohexanol , chemistry , thermodynamics , enthalpy of mixing , mixing (physics) , organic chemistry , physics , toluene , catalysis , quantum mechanics

Data on vapor‐liquid equilibrium and enthalpy of mixing H E are, obtained for the mixture 1, 3 dioxolane‐methylcyclohexane at 313.15 K (40.0°C). Correlation of the data is given by using Redlich‐Kister expressions and the excess functions G E = RT ( X 1 In γ 1 + X 2 In γ 2 ) and TS E = H E ‐ G E are thereby calculated. A comparison is made between this mixture and those formed by 1, 3 dioxolane with cyclohexanol and cyclohexanone.

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