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A fundamental study on recovery of copper with a cation exchange membrane: Part 2 — Transfer rate of copper and hydrogen ion through a cation exchange membrane
Author(s) -
Kojima Toshinori,
Furusaki Shintaro,
Saito Kyoichi
Publication year - 1982
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450600512
Subject(s) - copper , chemistry , nitric acid , sulfuric acid , membrane , inorganic chemistry , hydrogen , ion , ion exchange , diffusion , analytical chemistry (journal) , chromatography , thermodynamics , organic chemistry , biochemistry , physics
Abstract Transfer rates of copper and hydrogen ion through a cation exchange membrane were measured experimentally for the systems of Cu/H‐SO 4 and Cu/H‐NO 3 . Transfer rates of anions in the membrane were also measured, and they were negligible compared to those of the cations. Cupric ion and hydrogen ion transfer in a ratio of 1:2 and in opposite directions. The self‐diffusion coefficient of cupric ion in the membrane is obtained from the transfer rate of copper in high concentrations of sulfuric or nitric acid solutions using the equilibria data obtained in our previous work. The coefficient of the hydrogen ion is similarly obtained.