Transformation of propene into acrylonitrile with nitric oxide over nickel oxide alumina catalyst in a continuous stirred tank reactor | Zendy

Agbebavi James Thomas | Zendy; Rouleau Denis | Zendy; Pajonk Gerard | Zendy

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Transformation of propene into acrylonitrile with nitric oxide over nickel oxide alumina catalyst in a continuous stirred tank reactor

Author(s) -

Agbebavi James Thomas,

Rouleau Denis,

Pajonk Gerard

Publication year - 1982

Publication title -

the canadian journal of chemical engineering

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.404

H-Index - 67

eISSN - 1939-019X

pISSN - 0008-4034

DOI - 10.1002/cjce.5450600312

Subject(s) - propene , catalysis , acrylonitrile , nickel , oxide , nickel oxide , chemistry , atmospheric pressure , continuous stirred tank reactor , inorganic chemistry , propane , organic chemistry , copolymer , polymer , oceanography , geology

Catalytic transformation of propene (C 3 H 6 ) with nitric oxide (NO) over nickel oxide alumina catalyst (2NiO, Al 2 O 3 ) has been investigated using a continuous stirred tank reactor at temperatures varying from 270 to 400°C, under atmospheric pressure. The main products found were acrylonitrile (C 3 H 3 N) and carbon dioxide (CO 2 ). The rate of formation of C 3 H 3 N and the rate of disappearance of C 3 H 6 were both correlated by the same model based on a redox mechanism: r i = k i o k i r P NO P HC /( k i o P NO + k i r P HC ) The constants in the rate equation were expressed as a function of temperature.

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