Premium
Kinetics of the liquid phase reaction between carbon dioxide and diethanolamine
Author(s) -
Coldrey P. W.,
Harris I. J.
Publication year - 1976
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450540536
Subject(s) - diethanolamine , carbon dioxide , kinetics , chemistry , chemical kinetics , aqueous solution , reaction mechanism , electrochemical reduction of carbon dioxide , inorganic chemistry , reaction rate , catalysis , organic chemistry , carbon monoxide , physics , quantum mechanics
The kinetics of the reaction between carbon dioxide in aqueous solution and aqueous diethanolamine have been studied using the thermal flow method. The data indicate that the kinetics of the reaction is complex. The particular mechanism proposed consists of two reactions which initially compete for the available carbon dioxide. One of these reactions is reversible, and regenerates carbon dioxide as the overall reaction proceeds. The species participating in the proposed reversible reaction were not identifiable from the data obtained.