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Interpretation of experimental rates of reaction for multiple step chemical reaction systems: Part I: A general modelling procedure
Author(s) -
Lana I. G. Dalla,
Myint A.,
Wanke S. E.
Publication year - 1973
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450510508
Subject(s) - kinetic energy , consistency (knowledge bases) , interpretation (philosophy) , reaction rate , chemical reaction , chemical kinetics , experimental data , chemistry , thermodynamics , computer science , kinetics , mathematics , physics , statistics , organic chemistry , artificial intelligence , quantum mechanics , programming language , catalysis
Experimental kinetic data in a form equivalent to concentration‐time trajectories (or the corresponding rates of reaction) may be decomposed into rate data for the individual chemical reaction steps defining a chemical reaction network. When kinetic models are fitted to each set of single‐step rate data, the resulting single‐step kinetic models may be combined to formulate an overall kinetic model for the network. Such network‐kinetic models may exhibit consistency with both the apparent chemistry and the observed rate behaviour.