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Application of wilsonés equation to determination of vapor‐liquid equilibrium data and heats of mixing for non‐ideal solutions
Author(s) -
Tai Trinh Ba,
Ramalho Rubens S.,
Kaliaguine S.
Publication year - 1972
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450500616
Subject(s) - ternary operation , isothermal process , thermodynamics , mixing (physics) , binary number , ideal (ethics) , ideal solution , chemistry , vapor–liquid equilibrium , vapor pressure , physics , mathematics , computer science , arithmetic , quantum mechanics , programming language , philosophy , epistemology
A calculation technique, starting from total pressure data of binary systems and utilizing Wilsonés equation was developed, leading to isothermal vapor liquid equilibrium data for binary and ternary systems. Heats of mixing for ternary systems were also calculated from binary data.