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Heats of mixing for ternary systems: n ‐Alkanes + Two n ‐Alcohols
Author(s) -
Ramalho R. S.,
Ruel M.
Publication year - 1968
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450460615
Subject(s) - ternary operation , mixing (physics) , alkane , thermodynamics , binary number , ternary numeral system , chemistry , polar , component (thermodynamics) , organic chemistry , hydrocarbon , mathematics , physics , computer science , arithmetic , quantum mechanics , astronomy , programming language
Heats of mixing for 21 ternary systems of one n‐alkane + two n‐alcohols are reported at 25°C. Evaluation of four equations permitting the prediction of heats of mixing of ternary systems from binary data is made. Scatchard's modified equation for systems containing a polar component was found to be the most accurate.