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Diffusion in binary liquid mixtures at infinite dilution
Author(s) -
Lusis M. A.,
Ratcliff C. A.
Publication year - 1968
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.5450460519
Subject(s) - dilution , diffusion , binary number , thermodynamics , effective diffusion coefficient , statistical physics , mathematics , physics , medicine , arithmetic , radiology , magnetic resonance imaging
A correlation is presented for the mutual diffusion coefficient in a binary liquid system at infinite dilution. It has several advantages over previous correlations, and is recommended for diffusion in organic solvents. Some special cases where empirical correlations should be used with caution are discussed briefly.