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High‐performance photocatalysts for the selective oxidation of alcohols to carbonyl compounds
Author(s) -
Rangarajan Goutham,
Yan Ning,
Farnood Ramin
Publication year - 2020
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.23835
Subject(s) - photocatalysis , alcohol oxidation , catalysis , hazardous waste , environmentally friendly , nanotechnology , chemistry , biochemical engineering , materials science , organic chemistry , waste management , engineering , ecology , biology
With an increase in awareness about the need for green chemistry, there is a shift in focus towards identifying eco‐compatible technologies that can improve product yield and eliminate the use or generation of hazardous compounds. An immediate practical example of such an approach is the development of sustainable methods for alcohol oxidation as alternatives to the current processes that are energy intensive and rely on ecotoxic chemicals. In this regard, heterogeneous photocatalysis has been identified as a robust technique to catalyze reactions under benign conditions, which would otherwise require harsh synthesis routes. With the advent of materials sciences and nanotechnology, there has been a tremendous increase in the scope of applicability of photocatalysis in fine chemicals synthesis. Though an attractive choice, much of the fundamental information pertaining to catalyst activity, selectivity and reaction conditions for optimum conversion are still to be investigated for most of these systems. To this end, this review will encompass recent achievements in the selective photocatalytic oxidation of alcohols by harnessing solar radiation as a viable source of energy. The discussion will be arranged based on common types of photocatalysts reported in literature, namely metal oxides (eg, TiO 2 and ZnO, Nb 2 O 5 ), sulphides (eg, CdS, CuS, and Bi 2 S 3 ), and carbonaceous photocatalysts (eg, g ‐C 3 N 4 ). Several such candidates for photocatalysts will be discussed critically with the aim of providing useful insight into developing selective photocatalysts that can oxidize alcohols via eco‐friendly pathways along with high yields.