z-logo
Premium
NiNbO catalyst deposited on anodized aluminum monoliths for the oxidative dehydrogenation of ethane
Author(s) -
Santander José A.,
Boldrini Diego E.,
Pedernera Marisa N.,
Tonetto Gabriela M.
Publication year - 2017
Publication title -
the canadian journal of chemical engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.404
H-Index - 67
eISSN - 1939-019X
pISSN - 0008-4034
DOI - 10.1002/cjce.22800
Subject(s) - dehydrogenation , catalysis , materials science , chemical engineering , anodizing , coating , adsorption , ethylene , aluminium , x ray photoelectron spectroscopy , aqueous solution , inorganic chemistry , chemistry , metallurgy , nanotechnology , organic chemistry , engineering
Aluminum monoliths were used as substrates to prepare structured catalysts. A rough alumina layer was generated on the surface of the substrates by anodizing followed by hydrothermal treatments. The dip‐coating technique was used for coating the monolithic substrates. Aqueous suspensions with 0.15 and 0.30 g/g of Ni‐Nb mixed oxides catalysts were prepared for that purpose. Colloidal SiO 2 was added as a binder in order to obtain homogeneous and adherent coatings. The samples were characterized by SEM, TPR, XPS, XRD, and N 2 adsorption and tested in the oxidative dehydrogenation (ODH) of ethane to ethylene. The silica particles produced a drop in catalytic activity without affecting ethylene selectivity. The former effect was attributed mainly to a decrease in surface nickel concentration and an increase in reduction temperature. The presence of anodized aluminum substrates in the reaction environment did not have a significant influence on catalytic activity and product distribution, as observed for the coated monoliths used in this work, thus being a useful material to prepare structured catalysts for low‐temperature ethane ODH.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here