Henry's law constant for hydrogen in high temperature water with dissolved lithium and boron | Zendy

Giraudeau Franck | Zendy; Lister Derek H. | Zendy; Morris David R. | Zendy; Setthanan Uncharat | Zendy; Steward Frank R. | Zendy; Yang Lei Tai | Zendy

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Henry's law constant for hydrogen in high temperature water with dissolved lithium and boron

Author(s) -

Giraudeau Franck,

Lister Derek H.,

Morris David R.,

Setthanan Uncharat,

Steward Frank R.,

Yang Lei Tai

Publication year - 2008

Publication title -

the canadian journal of chemical engineering

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.404

H-Index - 67

eISSN - 1939-019X

pISSN - 0008-4034

DOI - 10.1002/cjce.20111

Subject(s) - boron , hydrogen , lithium (medication) , henry's law , thermodynamics , chemistry , constant (computer programming) , inorganic chemistry , analytical chemistry (journal) , materials science , aqueous solution , physics , environmental chemistry , organic chemistry , computer science , programming language , endocrinology , medicine

The results of measurement of the Henry's law constant are reported for solutions of H 2 in H 2 O, with dissolved lithium and boron, at high temperature (220 to ∼300°C). The experimental procedure involved the use of a palladium/hydrogen electrical resistance sensor to determine the hydrogen gas pressure in equilibrium with the hydrogen dissolved in the water. Values of $K_{\rm H}^\infty$ for the above solutions were lower than values for the solute‐free H 2 /H 2 O solutions. For conditions typical of a Pressurized Water Reactor (PWR) the lowering amounted to about 3%.

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