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One‐Step Synthesis of MIL‐53(Al)/Boehmite Composites
Author(s) -
Schwegler Johannes,
Fischer Marcus,
Paula Carolin,
Schulz Peter S.,
Hartmann Martin
Publication year - 2017
Publication title -
chemie ingenieur technik
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.365
H-Index - 36
eISSN - 1522-2640
pISSN - 0009-286X
DOI - 10.1002/cite.201700002
Subject(s) - boehmite , materials science , scanning electron microscope , reagent , nanoparticle , chemical engineering , composite material , metal organic framework , matrix (chemical analysis) , catalysis , aluminium , nanotechnology , chemistry , organic chemistry , adsorption , engineering
[EMIM][Hbdc] and [EMIM] 2 [bdc] were synthesized and successfully used in a one‐step synthesis procedure of MIL‐53(Al)/boehmite composites with unusual properties. The breathing effect typically observed for MIL‐53(Al) is not found and scanning electron microscopy confirms the presence of MIL‐53 nanoparticles in a boehmite matrix. The completely different characteristics of this MIL‐53 samples in comparison to hydrothermally synthesized MIL‐53(Al) clearly demonstrate the tremendous influence of variations of the reagents used for the syntheses of metal‐organic framework materials.