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Enantioselective epoxidation by an optically active hydroperoxide
Author(s) -
Hamann HansJürgen,
Höft Eugen,
Chmielewski Marek,
Maciejewski Sylvester
Publication year - 1993
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.530050511
Subject(s) - enantioselective synthesis , chemistry , optically active , enantiomer , enantiomeric excess , allylic rearrangement , epoxy , epoxide , organic chemistry , stereochemistry , catalysis
Enantioselective epoxidation of prochiral allylic alcohols with optically active 4,6‐di‐ O ‐acetyl‐2,3‐dideoxy‐α‐ D ‐threo‐hex‐2‐enopyranosyl hydroperoxide in the presence of Ti(O‐i‐Pr) 4 gives chiral epoxy alcohols with moderate enantiomeric excess. © 1993 Wiley‐Liss, Inc.
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