z-logo
Premium
Chirally sensitive collision induced dissociation of proton‐bound diastereomeric complexes of tryptophan and 2‐butanol
Author(s) -
Rebrov Oleksii,
Kulyk Kostiantyn,
Ryding Mauritz,
Thomas Richard D.,
Uggerud Einar,
Larsson Mats
Publication year - 2017
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22679
Subject(s) - chemistry , diastereomer , dissociation (chemistry) , collision induced dissociation , tryptophan , collision , proton , computational chemistry , stereochemistry , mass spectrometry , amino acid , chromatography , biochemistry , tandem mass spectrometry , physics , computer security , quantum mechanics , computer science
In this work we report the stereo‐dependent collision‐induced dissociation (CID) of proton‐bound complexes of tryptophan and 2‐butanol. The dissociation efficiency was measured as a function of collision energy in single collision mode. The homochiral complex was found to be less stable against CID than a heterochiral one. Additional gas dependence measurements were performed with diastereomeric complexes that confirm the findings.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here