Enantioselective Addition  of Diethylzinc to Aldehydes Catalyzed by Chiral  O , N , O ‐tridentate Phenol Ligands Derived From Camphor | Zendy

Lee DongSheng | Zendy; Chang ShuMing | Zendy; Ho ChunYing | Zendy; Lu TaJung | Zendy

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Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Chiral O , N , O ‐tridentate Phenol Ligands Derived From Camphor

Author(s) -

Lee DongSheng,

Chang ShuMing,

Ho ChunYing,

Lu TaJung

Publication year - 2016

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.22543

Subject(s) - diethylzinc , chemistry , enantioselective synthesis , camphor , phenol , catalysis , chirality (physics) , medicinal chemistry , organic chemistry , stereochemistry , chiral symmetry breaking , physics , quantum mechanics , quark , nambu–jona lasinio model

Chiral O,N,O‐tridentate phenol ligands bearing a camphor backbone were found to be effective chiral catalysts for the enantioselective addition of diethylzinc to aromatic aldehydes, resulting in high enantioselectivities (80–95% ee) at room temperature. Chirality 28:65–71, 2016 . © 2015 Wiley Periodicals, Inc.

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