Studies Towards the Synthesis of Medermycin via Dötz  Benzannulation | Zendy

Qu Chunrong | Zendy; Tang Erqing | Zendy; Loeppky Richard | Zendy; Deng Zixin | Zendy; Pulley Shon R. | Zendy; Hong Xuechuan | Zendy

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Studies Towards the Synthesis of Medermycin via Dötz Benzannulation

Author(s) -

Qu Chunrong,

Tang Erqing,

Loeppky Richard,

Deng Zixin,

Pulley Shon R.,

Hong Xuechuan

Publication year - 2015

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.22383

Subject(s) - chemistry , nitrile , chirality (physics) , carbene , halogenation , carbamate , organic chemistry , combinatorial chemistry , catalysis , medicinal chemistry , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , quark

The C ‐arylglycosides are available in enantiomerically pure form via the Dötz benzannulation reaction between Fischer alkenyl chromium carbene complexes and alkynes; it also could be converted to a precursor of medermycin by O ‐carbamate directed ipso bromination and nitrile substitution in good overall yields. Chirality 27:18–22, 2015 . © 2014 Wiley Periodicals, Inc.

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