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Synthesis of Novel Chiral Tridentate Schiff‐Base Ligands and Their Applications in Catalytic Asymmetric Henry Reaction
Author(s) -
Qiang GenRong,
Shen TianHua,
Zhou XiaoCong,
An XiaoXia,
Song QingBao
Publication year - 2014
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22369
Subject(s) - chemistry , schiff base , catalysis , chirality (physics) , adduct , enantioselective synthesis , combinatorial chemistry , organic chemistry , polymer chemistry , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , quark
A series of chiral tridentate Schiff‐bases were prepared and used as ligands in the catalytic asymmetric Henry reaction . Under the optimal conditions, a variety of arylaldehydes were smoothly converted into corresponding adducts with high yields (up to 98%) and excellent enantioselectivities (up to 97% ee ). Chirality 26: 780–783, 2014 . © 2014 Wiley Periodicals, Inc.