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Chiral Dirhodium(II) Carboxylates and Carboxamidates as Effective Chemzymes in Asymmetric Synthesis of Three‐Membered Carbocycles
Author(s) -
Adly Frady G.,
Ghanem Ashraf
Publication year - 2014
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22347
Subject(s) - cyclopropanation , chemistry , intramolecular force , stereochemistry , enantioselective synthesis , chirality (physics) , catalysis , organic chemistry , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
In this review the recent advances in the utilization of two of the most important classes of dirhodium(II) paddlewheel complexes, dirhodium(II) carboxylates and carboxamidates, as chemzymes in inter‐ and intramolecular asymmetric cyclopropanation , as well as cyclopropenation reactions are discussed. Chirality 26:692–711, 2014. © 2014 Wiley Periodicals, Inc