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Organic/Hybrid Nanoparticles and Single‐Walled Carbon Nanotubes : Preparation Methods and Chiral Applications
Author(s) -
Alhassen Haysem,
Antony Vijy,
Ghanem Ashraf,
Yajadda Mir Massoud Aghili,
Han Zhao Jun,
Ostrikov Kostya Ken
Publication year - 2014
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22321
Subject(s) - carbon nanotube , nanoparticle , nanotechnology , nanomaterials , hybrid material , chemistry , colloidal gold , carbon fibers , materials science , composite number , composite material
Nanoparticles are molecular‐sized solids with at least one dimension measuring between 1–100 nm or 10–1000 nm depending on the individual discipline's perspective. They are aggregates of anywhere from a few hundreds to tens of thousands of atoms which render them larger than molecules but smaller than bulk solids. Consequently, they frequently exhibit physical and chemical properties somewhere between. On the other hand, nanocrystals are a special class of nanoparticles which have started gaining attention recently owing to their unique crystalline structures which provide a larger surface area and promising applications including chiral separations . Hybrid nanoparticles are supported by the growing interest of chemists, physicists, and biologists, who are researching to fully exploit them. These materials can be defined as molecular or nano‐composites with mixed (organic or bio) and inorganic components, where at least one of the component domain has a dimension ranging from a few Å to several nanometers. Similarly, and due to their extraordinary physical, chemical, and electrical properties, single‐walled carbon nanotubes have been the subject of intense research. In this short review, the focus is mainly on the current well‐established simple preparation techniques of chiral organic and hybrid nanoparticles as well as single‐walled carbon nanotubes and their applications in separation science. Of particular interest, cinchonidine, chitosan, and β‐CD‐modified gold nanoparticles (GNPs) are discussed as model examples for organic and hybrid nanoparticles. Likewise, the chemical vapor deposition method, used in the preparation of single‐walled carbon nanotubes , is discussed. The enantioseparation applications of these model nanomaterials is also presented. Chirality 26:683–691, 2014 . © 2014 Wiley Periodicals, Inc.

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