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Conformational Stable Alleno‐Acetylenic Cyclophanes Bearing Chiral Axes
Author(s) -
Lahoz Inmaculada R.,
CastroFernández Silvia,
NavarroVázquez Armando,
AlonsoGómez José Lorenzo,
Magdalena Cid M.
Publication year - 2014
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22313
Subject(s) - chemistry , supramolecular chemistry , chirality (physics) , supramolecular chirality , anthracene , stereochemistry , cyclophane , pyridine , planar chirality , enantioselective synthesis , crystallography , crystal structure , organic chemistry , catalysis , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
The design and synthesis of chiral cyclophanes containing signaling functional groups as an integral part of the macrocyclic framework offer promising possibilities for chiral sensing, molecular recognition , and chiral supramolecular architectures. Our research group has been involved in the construction and study of chiroptical properties of several allenic meta‐ and para‐cyclophanes bearing anthracene and pyridine rings as spacers. A revision of our results is presented. Chirality 26:563–573, 2014. © 2014 Wiley Periodicals, Inc.