Determination of the Absolute Stereochemistry of Two New Aristophyllene Sesquiterpenes: A Combined Theoretical and Experimental Investigation | Zendy

Wu RuiBo | Zendy; Cheng ZhongBin | Zendy; Han QingHua | Zendy; Lin TingTing | Zendy; Zhou JingWei | Zendy; Tang GuiHua | Zendy; Yin Sheng | Zendy

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Determination of the Absolute Stereochemistry of Two New Aristophyllene Sesquiterpenes: A Combined Theoretical and Experimental Investigation

Author(s) -

Wu RuiBo,

Cheng ZhongBin,

Han QingHua,

Lin TingTing,

Zhou JingWei,

Tang GuiHua,

Yin Sheng

Publication year - 2014

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.22294

Subject(s) - chemistry , chirality (physics) , stereochemistry , absolute configuration , absolute (philosophy) , computational chemistry , chiral symmetry , philosophy , epistemology , physics , quantum mechanics , nambu–jona lasinio model , quark

Aristoyunnolins G ( 1 ) and H ( 2 ), two new diastereoisomeric sesquiterpenes featuring a rare aristophyllene skeleton, were isolated from the traditional Chinese medicine Aristolochia yunnanensis . Their absolute stereochemistry involving three chiral centers was determined by combined chemical, spectral, and Density Functional Theory (DFT) calculation methods. Chirality 26:189–193, 2014 . © 2014 Wiley Periodicals, Inc.

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