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Enantioselective Organocatalytic Oxaziridination of N‐Tosyl Aldimine Catalyzed by Cinchona Alkaloid‐Ester Derivatives
Author(s) -
Jin Ying,
Zhang Tianyi,
Zhang Wei,
Chang Sheng,
Feng Bo
Publication year - 2014
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22283
Subject(s) - cinchona , chemistry , enantioselective synthesis , aldimine , catalysis , tosyl , alkaloid , organocatalysis , organic chemistry , cinchona alkaloids , stereochemistry
A series of cinchona alkaloid‐ester derivatives was synthesized and applied to catalyze the enantioselective oxaziridination of aryl aldimines with m ‐CPBA. The ( R,R )‐oxaziridines were obtained in good yields with high enantiomeric excess (ee) values (up to 98%). Chirality 26:150–154, 2014 . © 2014 Wiley Periodicals, Inc.
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