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α‐Amino‐Oximes Based on Optically Pure Limonene: A New Ligands Family for Ruthenium‐Catalyzed Asymmetric Transfer Hydrogenation
Author(s) -
Ibn El Alami Mohammed Samir,
El Amrani Mohamed Amin,
Dahdouh Abdelaziz,
Roussel Pascal,
Suisse Isabelle,
Mortreux André
Publication year - 2012
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.22073
Subject(s) - chemistry , ruthenium , enantioselective synthesis , oxime , transfer hydrogenation , bifunctional , chirality (physics) , catalysis , limonene , combinatorial chemistry , organic chemistry , stereochemistry , chiral symmetry breaking , physics , chromatography , quantum mechanics , essential oil , nambu–jona lasinio model , quark
A new family of bifunctional, optically pure α‐amino‐oxime ligands based on ( R )‐limonene has been synthesized and used as chiral inducers for enantioselective hydrogen transfer reactions on various ketones in the presence of ruthenium catalysts. The X‐ray structures of Ru―amino‐oxime complexes are also described. Chirality 24:675–682, 2012 . © 2012 Wiley Periodicals, Inc.