Enantioselective sensing of chiral amino alcohols with a stereodynamic arylacetylene‐based probe | Zendy

Iwaniuk Daniel P. | Zendy; Bentley Keith W. | Zendy; Wolf Christian | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Enantioselective sensing of chiral amino alcohols with a stereodynamic arylacetylene‐based probe

Author(s) -

Iwaniuk Daniel P.,

Bentley Keith W.,

Wolf Christian

Publication year - 2012

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.22066

Subject(s) - chemistry , enantioselective synthesis , chirality (physics) , organic chemistry , organocatalysis , catalysis , computational chemistry , combinatorial chemistry , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark

Enantioselective induced circular dichroism analysis of amino alcohols has been accomplished using a conformationally flexible arylacetylene‐based probe exhibiting two terminal aldehyde groups. The chirality of the amino alcohol substrates is imprinted on the stereodynamic receptor upon [1 + 2] condensation, which ultimately generates a strong chiroptical response. The distinct induced circular dichroism effects of the diimines obtained can be used for enantioselective sensing and enantiomeric excess determination of a wide range of substrates. Chirality 24:584–589, 2012 . © 2012 Wiley Periodicals, Inc.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research