Synthesis and structural elucidation of novel camphor‐derived thioureas | Zendy

Grošelj Uroš | Zendy; Golobič Amalija | Zendy; Stare Katarina | Zendy; Svete Jurij | Zendy; Stanovnik Branko | Zendy

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Synthesis and structural elucidation of novel camphor‐derived thioureas

Author(s) -

Grošelj Uroš,

Golobič Amalija,

Stare Katarina,

Svete Jurij,

Stanovnik Branko

Publication year - 2012

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.21999

Subject(s) - camphor , chemistry , thiourea , chirality (physics) , methylene , stereochemistry , organic chemistry , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark

Nine novel (+)‐camphor‐derived thioureas have been prepared. 3‐((Dimethylamino)methylene)camphor ( 2 ) served as the common precursor for the preparation of both, 2‐thiourea 15 , 16 , 17 , 18 , 19 , 20 and 3‐thiourea functionalized camphor derivatives 6 , 7 / 7' , respectively. Starting from 2 , the latter were prepared in two or three steps whereas the former in five steps, respectively. Configuration of all novel compounds has been meticulously determined using NMR techniques and/or single crystal X‐ray crystallography. Chirality, 2012. © 2012 Wiley Periodicals, Inc.

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