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Chiral recognition of diastereomeric 6‐cedrols by vibrational circular dichroism
Author(s) -
Gordilloromán Bárbara,
Camachoruiz Jorge,
Bucio María A.,
JosephNathan Pedro
Publication year - 2012
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.21036
Subject(s) - chemistry , circular dichroism , vibrational circular dichroism , diastereomer , chirality (physics) , epimer , crystallography , stereochemistry , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
The use of vibrational circular dichroism spectroscopy for the chiral recognition of the two epimers of 6‐cedrol, tricyclic sesquiterpenes, which contains oxygen as the heaviest atom, is shown. Bands in the 1500–850 cm −1 region of the spectra were analyzed to calculate the anisotropy factors ( g ), which provided the regions of maximum circular dichroism effect for each epimer. Chirality, 2012. © 2011 Wiley Periodicals, Inc.