Molecular tweezers for enantiodiscrimination in NMR: Di‐( R,R )‐1‐[10‐(1‐hydroxy‐2,2,2‐trifluoroethyl)‐9‐anthryl]‐2,2,2‐trifluoroethyl benzenedicarboxylates | Zendy

Gil Sergio | Zendy; PalominoSchätzlein Martina | Zendy; Burusco Kepa Koldo | Zendy; Jaime Carlos | Zendy; Virgili Albert | Zendy

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Molecular tweezers for enantiodiscrimination in NMR: Di‐( R,R )‐1‐[10‐(1‐hydroxy‐2,2,2‐trifluoroethyl)‐9‐anthryl]‐2,2,2‐trifluoroethyl benzenedicarboxylates

Author(s) -

Gil Sergio,

PalominoSchätzlein Martina,

Burusco Kepa Koldo,

Jaime Carlos,

Virgili Albert

Publication year - 2010

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.20786

Subject(s) - chemistry , stereochemistry , molecular tweezers , crystallography , supramolecular chemistry , crystal structure

A series of new chiral molecular tweezers, di‐( R,R )‐1‐[10‐(1‐hydroxy‐2,2,2‐trifluoroethyl)‐9‐anthryl]‐2,2,2‐trifluoroethyl phthalate (2), isophthalate (3) and terephthalate (4), were synthesized and their structure studied by NMR and molecular mechanics. Their effectiveness as chiral solvating agents for the determination of the enantiomeric purity of chiral compounds using NMR was demonstrated. Chirality 2010. © 2009 Wiley‐Liss, Inc.

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