Easily recyclable chiral polymeric Mn(III) salen complexes for oxidative kinetic resolution of racemic secondary alcohols | Zendy

Kureshy Rukhsana I. | Zendy; Ahmad Irshad | Zendy; Pathak Kavita | Zendy; Khan NoorUl H. | Zendy; Abdi Sayed H. R. | Zendy; Prathap Jaya K. | Zendy; Jasra Raksh V. | Zendy

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Easily recyclable chiral polymeric Mn(III) salen complexes for oxidative kinetic resolution of racemic secondary alcohols

Author(s) -

Kureshy Rukhsana I.,

Ahmad Irshad,

Pathak Kavita,

Khan NoorUl H.,

Abdi Sayed H. R.,

Prathap Jaya K.,

Jasra Raksh V.

Publication year - 2007

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.20387

Subject(s) - kinetic resolution , chemistry , catalysis , kinetic energy , oxidative phosphorylation , oxidative addition , organic chemistry , polymer chemistry , enantioselective synthesis , biochemistry , physics , quantum mechanics

Chiral polymeric Mn(III) salen complexes were used efficiently for oxidative kinetic resolution of racemic secondary alcohols at room temperature. High chiral purity (ee; >99%) was achieved for the oxidative kinetic resolution of racemic secondary alcohols with 0.6 mol % catalyst loading in 60 min. The catalyst was easily recycled for five successive catalytic experiments. Chirality, 2007. © 2007 Wiley‐Liss, Inc.

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