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Easily recyclable chiral polymeric Mn(III) salen complexes for oxidative kinetic resolution of racemic secondary alcohols
Author(s) -
Kureshy Rukhsana I.,
Ahmad Irshad,
Pathak Kavita,
Khan NoorUl H.,
Abdi Sayed H. R.,
Prathap Jaya K.,
Jasra Raksh V.
Publication year - 2007
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.20387
Subject(s) - kinetic resolution , chemistry , catalysis , kinetic energy , oxidative phosphorylation , oxidative addition , organic chemistry , polymer chemistry , enantioselective synthesis , biochemistry , physics , quantum mechanics
Chiral polymeric Mn(III) salen complexes were used efficiently for oxidative kinetic resolution of racemic secondary alcohols at room temperature. High chiral purity (ee; >99%) was achieved for the oxidative kinetic resolution of racemic secondary alcohols with 0.6 mol % catalyst loading in 60 min. The catalyst was easily recycled for five successive catalytic experiments. Chirality, 2007. © 2007 Wiley‐Liss, Inc.