Mutual kinetic separation of isotopomers of pentafluorophenyl 2‐phenyl propionate using quasi‐enantiomeric oxazolidinones | Zendy

Chavda Sameer | Zendy; Coumbarides Gregory S. | Zendy; Dingjan Marco | Zendy; Eames Jason | Zendy; Flinn Anthony | Zendy; Northen Julian | Zendy

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Mutual kinetic separation of isotopomers of pentafluorophenyl 2‐phenyl propionate using quasi‐enantiomeric oxazolidinones

Author(s) -

Chavda Sameer,

Coumbarides Gregory S.,

Dingjan Marco,

Eames Jason,

Flinn Anthony,

Northen Julian

Publication year - 2007

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.20364

Subject(s) - chemistry , isotopomers , enantiomer , chirality (physics) , propionate , enantiomeric excess , stereochemistry , combinatorial chemistry , computational chemistry , organic chemistry , enantioselective synthesis , catalysis , molecule , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , quark

Mutual separation of an equimolar mixture of quasi‐enantiomeric [D, 13 C]‐labeled isotopomers of pentafluorophenyl 2‐phenylpropionate can be achieved efficiently by use of two quasi‐enantiomeric Evans' oxazolidinones. The levels of stereocontrol were high, leading to products with predictable configurations. Chirality, 2007. © 2007 Wiley‐Liss, Inc.

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